By Eric R. Scerri
This e-book represents a suite of papers from one of many founders of the recent Philosophy of Chemistry. it's only the second one single-author choice of papers at the Philosophy of Chemistry.
the writer is the editor-in-chief of Foundations of Chemistry, the top magazine within the box. He has lately won around the world luck together with his booklet at the periodic desk of the weather titled The Periodic desk: Its tale and Its value. This quantity presents an in-depth exam of his extra philosophical and ancient paintings during this region and additional afield.
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Extra info for Collected Papers on Philosophy of Chemistry
To sum up, we have argued that the periodic law is regarded as highly law-like in chemistry and that there exist no exceptions to it. Yet, the nature of the law is such that it cannot be captured by a simple numerical relationship,22 and the regularity it captures cannot be expressed in nomological fashion using non-chemical concepts. The law expresses an approximate trend among the properties of the elements and their compounds. But if one attempts to express this trend numerically, such a relationship is found to hold only approximately.
Primas, as quoted earlier, says that we can calculate certain molecular properties, but we cannot point to something in the mathematical expressions which can be identified with bonding. The concept of chemical bonding seems to be lost in the process of reduction (Primas 1983). Woolley, to cite another example, has raised q great deal of interest in saying that chemical structure cannot be found in the pure quantum mechanical formalism applied to a chemical system. Structure, he tells us, is imposed by using the Born-Oppenheimer approximation (Woolley 1978).
The sad fact for chemistry, moreover, is that only the Schrodinger equation for the hydrogen atom possesses an exact solution. This system is hardly of interest to “real chemists”, whose concerns range over the remaining hundred or so elements in the periodic table. And even if one were to restrict attention to the element hydrogen, chemists are more frequently concerned with diatomic hydrogen (H2) rather than the highly reactive hydrogen atom which is the only system to have been truly captured by quantum mechanics.